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TRI-p-METHANE REARRANGEMENT |
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Staff: |
Vladimír Církva, Stanislav Relich, Lenka Slavětínská, Leona Vlková |
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External co-workers: |
Howard E. Zimmerman (University of Wisconsin-Madison, Chemistry Department); Jaroslav Kvíčala (Institute of Chemical Technology (ICT) Prague, Department of organic chemistry) |
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Financing, funding: |
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What is tri-p-methane rearrangement?
Photochemical reaction of 3-vinyl-1,4-dienes leading to 3-vinyl cyclopentenes:
Solved problematics:
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Fundamental research on tri-p-methane rearrangement
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Effect of substituents on regioselectivity of tri-p-methane rearrangement
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Quantum-chemical calculations on tri-p-methane rearrangement
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Publications:
[1] Zimmerman, H.E.; Církva, V.: Org. Lett. 2 (2000) 2365-2367. The tri-p-methane rearrangement: Mechanistic and exploratory organic photochemistry.
[2] Zimmerman, H.E.; Církva, V.; Jiang, L.: Tetrahedron Lett. 41 (2000) 9585-9587. A ground state Tri-p-methane rearrangement.
[3] Zimmerman, H.E.; Církva, V.: J. Org. Chem. 66 (2001) 1839-1851 and supporting inf. Excited- and ground-state versions of the Tri-p-methane rearrangement: Mechanistic and exploratory organic photochemistry.
[4] Církva, V., Zimmerman H.E.: Chem. Listy 95 (2001) 746-747. Tri-p-methanový přesmyk. (Tri-p-methane rearrangement).
[5] Zimmerman, H.E.; Novak, T.: J. Org. Chem. 68 (2003) 5056-5066. Regioselectivity of the tri-p-methane rearrangement: Mechanistic and exploratory organic photochemistry.
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