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Diffusion of constituents in Mg-based advanced alloys and composites
Investigator: Mgr. Ivo Stloukal, Dr.
Number of Project: 106/05/2115
Agency: Czech Science Foundation
Duration: 01. 01. 2005 - 31. 12. 2007
The aim of the present project is to obtain radiotracer diffusion coefficients in four commercial alloys. The diffusion coefficients of 67Ga, 114mIn, 54Mn, 124Sb and 65Zn will be measured in AZ91 alloy (Mg-Al-Zn-Mn) and in composite AZ91+Saffil, the diffusion coefficients of 110mAg, 139Ce, 88Y and 65Zn will be measured in QE22 alloy (Mg-Ag-RE-Zr) and in composite QE22+Saffil. Measurements carried out at several temperatures will give activation energy and frequency factors of lattice diffusion. Experiments done with alloys of equal chemical composition and similar microstructure, but once with and once without short-fibers reinforcement will provide an assessment of diffusivities along the interphase fiber/matrix boundaries. The result obtained may be utilized for optimization of technological parameters in fabrication ad/or in thermal treatment of alloys under study in technical practice.
Publications:
J. Čermák and I. Stloukal: Zn Diffusion in Binary Base of Light Mg-Al Alloys. Def. Dif. For. 263, 2007, 165. (Presented as poster on D&T 06, 9th Seminar on Diffusion and Thermodynamics in Materials, September 13-15, 2006, Brno, Czech Republic)
J. Čermák and I. Stloukal: 65Zn Diffusion in a Two-Phase Eutectic Mg - 33 vt.% Al. METAL 2006 - 15th International Metallurgical & Material Conference, Hradec nad Moravicí, Czech Republic, May 23-25 2006, CD-ROM.
J. Čermák and I. Stloukal: Heterodiffusion of 65Zn in Binary Mg - x Al Alloys and in A Commercial Alloy AZ91. METAL 2006 - 15th International Metallurgical & Material Conference, Hradec nad Moravicí, Czech Republic, May 23-25 2006, CD-ROM.
J. Čermák and I. Stloukal: Diffusion of 65Zn in Mg and in Mg - x Al Solid Solutions. phys. stat. sol. (a) 203, 2006, 2386.
J. Čermák and I. Stloukal (Eds.): D&T '06 IXth Seminar on Diffusion and Thermodynamics of Materials Book of Abstracts, IPM AS CR, Brno, 2006.
J. Čermák and I. Stloukal: Zn Diffusion in Binary Base of Light Mg-Al Alloys. D&T '06 IXth Seminar on Diffusion and Thermodynamics of Materials Book of Abstracts, 2006, p. 44.
J. Čermák and I. Stloukal: Diffusion of 65Zn in the Mg17Al12 Intermetallic Compound and in the Mg-33.4 wt.% Eutectic. Int. J. Mat. Res. (formerly Z. Metallkd.) 97, 2006, 1476.
J. Čermák and I. Stloukal: Diffusion and Thermodynamics of Materials. Trans Tech Publications, Switzerland, 2007.
J. Čermák and I. Stloukal: Diffusion of 65Zn in AZ91 and in QE22 Reinforced by Saffil Fibers. Compos. Sci. Technol. 68, 2008, 417.
J. Čermák and I. Stloukal: Mechanism of 88Y Diffusion in QE22 Alloy. METAL 2008 - 17th International Metallurgical & Material Conference, Hradec nad Moravicí, Czech Republic, May 13-15 2008, CD-ROM.
I. Stloukal and J. Čermák: Diffusion of Zinc in Two-phase Mg-Al Alloy. Def. Dif. For. 263, 2007, 189. (Presented as poster on D&T 06, 9th Seminar on Diffusion and Thermodynamics in Materials, September 13-15, 2006, Brno, Czech Republic)
I. Stloukal and J. Čermák: Diffusion of Zinc in Two-Phase Mg - Al Alloy. D&T '06 IXth Seminar on Diffusion and Thermodynamics of Materials Book of Abstracts, 2006, p. 50.
I. Stloukal and J. Čermák: Influence of Interfaces upon the Self-Diffusion in AZ91 Alloy Reinforced by Saffil Short Fibres. Mat. Sci. For. 567-568, 2008, 249.
I. Stloukal and J. Čermák: Tracer Diffusion of 65Zn, 110mAg and 88Y in QE22 Metal Matrix Composite. J. Alloy Compd. 471, 2009, 83.
I. Stloukal and J. Čermák: Silver Diffusion in Commercial QE22 Magnesium Alloy with Saffil Fiber - Compos. Sci. Tech. 68, 2008, 2799.
I. Stloukal and J. Čermák: Silver Self-Diffusion in Al2O3/QE22 Magnesium Alloy Matrix Composite. Def. Dif. For. 283-286, 2009, 155. (Presented as poster on DSL 2008, 4th International Conference on Diffusion in Solids and Liquids, July 9-11, 2008, Barcelona, Spain)
I. Stloukal and J. Čermák: Diffusion of 65Zn in AZ91 and QE22 Alloys with Saffil Reinforcement - Influence of Interfaces Matrix/Saffil. Def. Dif. For. 289-292, 2009, 145. (Presented as poster on DIMAT 2008, 7th International Conference on Diffusion in Materials, October 28-31, 2008, Lanzarote, Canary Islands, Spain)
Last update
11. 11. 2009