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Department of Photochemistry, Spectroscopy and Ion Chemistry

 Oddělení teoretické chemie    Oddělení fotochemie, spektroskopie a iontové chemie    Oddělení biofyzikální chemie    Oddělení struktury a dynamiky v katalýze    Oddělení syntézy a katalýzy    Oddělení elektrochemických materiálů    Oddělení elektrokatalýzy    Oddělení molekulární elektrochemie   

Ph.D. Studies

The themes of Ph.D. projects in the Institute are given as follows:
Chemical reactions of ions in gaseous phase and in collisions with surfaces.
Experimental investigation of elementary chemical reactions of ions with molecules in the gas phase and in collisions with solid surfaces using an instrument for studies of ion diffraction in particle beams. Investigation of ion reactions in a gas stream.
Prof RNDr. HERMAN Zdeněk, DrSc., RNDr. ŠPANĚL Patrik, Dr. rer. nat.

Modification of solid surfaces by ion beams.
Investigation of the ion beam effects on surface chemistry by electron spectroscopy methods using the most advanced instrument (Scienta ESCA 310, Sweden). Molecular dynamics calculations simulating the ion-surface interaction.
RNDr. BASTL Zdeněk, CSc.

Nondestructive concentration depth profiling by XPS.
Nondestructive determination of the surface concentration gradients at solid surfaces modified by ion and laser beams using angle resolved photoelectron spectroscopy and lineshape analysis, scattering of electrons in solids.
RNDr. BASTL Zdeněk, CSc.

Laser photoacoustic spectrometry and its application to simulation of air pollution in a wind tunnel.

Doc. RNDr. CIVIŠ Svatopluk, CSc., Doc. Ing. ZELINGER Zdeněk, CSc.

Dynamics and structure of small ionic clusters studied with high resolution IR spectroscopy.

Doc. RNDr. CIVIŠ Svatopluk, CSc., Doc. Ing. ZELINGER Zdeněk, CSc.

Construction of an ultra-fast MID-IR and IR laser diode spectrometer based on nonlinear optical effects.

Doc. RNDr. CIVIŠ Svatopluk, CSc., Doc. Ing. ZELINGER Zdeněk, CSc.

Photochemistry in a matrix of noble gases. Chemical dynamics of molecules trapped in solid matrices studied with spectroscopic techniques and excimer

Doc. RNDr. CIVIŠ Svatopluk, CSc.

Study of new types of superconducting materials using laser ablation technique.

Doc. RNDr. CIVIŠ Svatopluk, CSc., RNDr. KUBÁT Pavel, CSc.

Interaction of porphyrins with biopolymers.
Experimental investigation of novel porphyrins, their complexes with DNA and proteins. Laser kinetic spectrosco[py of photoinduced processes.
RNDr. KUBÁT Pavel, CSc.

High resolution molecular spectroscopy: hyperfine structure of rotation levels in degenerated vibrational states.
Theoretical interpretation of sub-Doppler hyperfine spectroscopy. Study of effects of the nuclear quadrupole-nuclear spin rotation and of nuclear spin-spin interactions.
Prof. RNDr. URBAN Štěpán, CSc.

Photodissociation studies of free clusters and nanoparticles of atmospheric relevance
A unique molecular beam apparatus is used to generate a beam of free clusters and nanoparticles in vacuum. Photodissociation and photochemistry of various molecules in the clusters is studied with a modern versatile UV-laser system. In this project clusters of atmospheric relevance, which play a role in, e.g., ozone depletion process, will be studied: ice nanoparticles doped with polutant molecules (hydrogen halides, HNO3, NOx, etc.). Theoretical calculations will be exploited in these studies too.
Mgr. FÁRNÍK Michal, Ph. D., Mgr. SLAVÍČEK Petr, Ph. D.

Photochemistry of small biomolecules in cluster environments
In relevance to biophysics and biochemistry photochemistry of small isolated gas phase biomolecules has been investigated. A detailed information about the photochemical behavior of the real systems in the nature can be provided by studies of these processes in cluster environments. A unique molecular beam apparatus is used to generate a beam of free clusters in vacuum, and the photochemistry of the various molecules in the clusters is studied with a modern versatile UV-laser system.
Mgr. FÁRNÍK Michal, Ph. D., Ing. POTERYA Viktoriya, Ph. D.

Implementation of imaging technique in cluster photodissociation studies
A novel experimental method -Ion Imaging- will be implemented in our cluster beam apparatus for photodissociation studies of clusters and nanoparticles. A small independent molecular beam apparatus will be built in the course of this project for development of the new method. The new technique will be used in studies of free clusters and nanoparticles namely of atmospheric and biological relevance.
Mgr. FÁRNÍK Michal, Ph. D., Mgr. VOTAVA Ondřej, Ph. D.

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