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Organic Chemistry (2009)

HomeTopics of Ph.D. ProjectsArchive - 2009Organic Chemistry (2009)
Tutor Dr. habil. Ullrich Jahn
Team

Ullrich Jahn

Topic Oxidative tandem Michael additions/radical cyclizations for the stereoselective construction of highly functionalized carbocycles
Faculty FCHT / FPBT VŠCHT, PřF UK
Abstract

Addition/cyclization reactions are an attractive strategy for the stereoselective construction of highly functionalized carbocycles. In contrast to traditional methodology, which employs mostly a single intermediate type or pericyclic reactions, the project will explore new ways of using multiple intermediate types like enolates, radicals and carbocations in a defined order to approach multifunctional carbocycles stereoselectively. This methodology should hold promise in the total synthesis of natural products.