Fyzikální ústav Akademie věd ČR

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Research at Department 12

Technology of material elaborationResearch subjects

  • Preparation of novel ceramic materials, e.g. EuTiO3
  • Single crystal growth, e.g. piezoelectric KIO3
  • Soft chemistry technology, e.g. filling nanoporous materials with ferroelectrics

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Time-resolved terahertz spectroscopyResearch subjects

  • Semiconductors for ultrafast optoelectronics
  • Charge carrier transport in disordered and nanostructures semiconductors

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Terahertz technologyResearch subjects

  • Tunable materials and structures for THz applications
  • THz near field microscopy

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Liquid crystalsResearch subjects

  • Ferroelectric and antiferroelectric structures in compounds with chiral rod-like and non-chiral bent-shaped molecules
  • Dielectric, electrooptic and optical properties and properties of relaxational modes in polar liquid crystals
  • Chirality and surface interactions of liquid crystalline phases
  • Defects in ferroelectric and antiferroelectric phases and their behavior in electric field
  • Photoelectric effect in photosensitive liquid crystals
  • Search for liquid crystalline monomers for synthesis of polar dimers and polymers

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Ferroelectricity and phase transitionsResearch subjects

  • Dynamics of structural (namely ferroelectric) phase transitions: experiment and theory
  • Multiferroic materials
  • Ferroelectric heterostructures and strained films
  • Polar clusters dynamics in relaxor ferroelectrics
  • Effective medium theory for dielectric and piezoelectric properties
  • Domain walls and domain structures
  • Development of crystallographic databases, structural characterization of novel phase transitions

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Ferroelectric phase transition in tensile-stressed SrTiO3 thin films and heterostructures driven by an electric-field tunable soft phonon modeSelected results

Theoretically predicted ferroelectric phase induced by tensile stress was confirmed in SrTiO3 epitaxial films and SrTiO3/DyScO3 heterostructures on DyScO3 substrates, prepared in top world laboratories. It is driven near 270 K by a soft phonon mode in the THz range which in the whole measured temperature region of 20-300 K couples to an overdamped excitation of order-of-magnitude lower frequency (obviously of strong anharmonic origin) and is tunable by electric field.  Celý text >>

Magnetoelectric multiferroicsSelected results

We have investigated the magnetoelectric effect in BiFeO3 and observed rather a large change of permittivity with magnetic field at high temperatures, where the sample becomes partially conducting due to defects. However, in this case the magnetoelectric effect is not intrinsic, i.e. due to coupling of polarization and magnetization, but due to combination of magnetoresistance and Maxwell-Wagner polarization effect (see S. Kamba et al., Phys. Rev. B 75, 024403 (2007)).  Celý text >>

Piezoelectric response of nanotwinned BaTiO3Selected results

Computer simulations based on Ginzburg-Landau-Devonshire theory are used to investigate piezoelectric response of tetragonal BaTiO3 crystals. We have shown that piezoelectric response of twinned BaTiO3 increases with increasing density of 90° domain walls. A considerable enhancement of the longitudinal piezoelectric coefficient is predicted for domain sizes below 50 nm.  Celý text >>

A nematic-polar columnar phase sequence in new bent-shaped liquid crystals based on a 7-hydroxynaphtalene-2-carboxylic acid coreSelected results

Series of 15 new liquid crystalline compounds have been synthesized and studied composed of non-symmetrical bent-shaped molecules based on a 7-hydroxynaphtalene-2-carboxylic acid, the central naphtalene core being laterally substituted by chlorine or the methyl group. Studies of textures in planar samples, calorimetric study, X-ray diffraction and dielectric measurements enabled to establish mesomorphic properties (ie. phase transitions and sequences of phases) of these compounds. The studied compounds exhibit the antiferroelectric B2 phase and relatively scarce polar columnar phases.  Celý text >>

First photoresponsive liquid-crystalline materials with small layer shrinkage at the transition to the ferroelectric phaseSelected results

A new series of new multifunctional materials with the azo-group in the molecular core has been prepared, which exhibit ferroelectric properties and are photosensitive. With these materials (known as photoferroelectrics) the illumination by visible light can change their electric and optical properties. After the light is switched off their properties are restored to the original state. Such materials offer a series of applications in optoelectronics or photonics.  Celý text >>

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