THE SECOND

KOREAN-CZECH JOINT SYMPOSIUM

ON MACROMOLECULAR CHEMISTRY

DECEMBER 1-2, 1998

INSTITUTE OF MACROMOLECULAR CHEMISTRY

ACADEMY OF SCIENCES OF THE CZECH REPUBLIC, PRAGUE

PROCEEDINGS

SPONSORED BY

ACADEMY OF SCIENCES OF THE CZECH REPUBLIC

KOREA SCIENCE AND ENGINEERING FOUNDATION

MACRO SERIES

Published by

Institute of Macromolecular Chemistry

Academy of Sciences of the Czech Republic

Department of Scientific Information

Heyrovský Sq. 2

162 06 Prague 6, Czech Republic

Jaroslav Kahovec

Editor of MACRO series

Volume K70

ISBN 80-85009-33-1


Symposium Chairmen

Jung-Il Jin

Korea University

Seoul, Republic of Korea

Karel Ulbrich

Institute of Macromolecular Chemistry

Academy of Sciences of the Czech Republic

Prague, Czech Republic

Scientific Programme Committee

Jiří Michálek (Chairman)

Jiří Dybal

Miroslav Janata

Petr Vlček

Organizing Committee

Jaromír Lukáš (Chairman)

Jaroslav Kahovec (Editor)

Eva Grisová

Dana Kotíková

Pavel Čefelín

Marie Rodová

Sponsors

Academy of Sciences of the Czech Republic

Korea Science and Engineering Foundation





List of Participants

Jung-Il Jin (Korea University)

Won-Jei Cho (Pusan National University)

Choon Ho Do (Sunchon National University)

Cheol Eui Lee (Korea University)

Hoosung Lee (Sogang University)

Myonsoo Lee (Yonsei University)

Su-Moon Park (Pohang University)

Yong Kiel Sung (Dongguk University)

Karel Ulbrich (Institute of Macromolecular Chemistry)

Miroslav Bleha (Institute of Macromolecular Chemistry)

Jiří Dybal (Institute of Macromolecular Chemistry)

Ivan Fortelný (Institute of Macromolecular Chemistry)

Jaroslav Kříž (Institute of Macromolecular Chemistry)

Jan Lokaj (Institute of Macromolecular Chemistry)

Jaromír Lukáš (Institute of Macromolecular Chemistry)

Jiří Michálek (Institute of Macromolecular Chemistry)

Stanislav Nešpůrek (Institute of Macromolecular Chemistry)

David Oupický (Institute of Macromolecular Chemistry)

Michal Pechar (Institute of Macromolecular Chemistry)

Jiří Pfleger (Institute of Macromolecular Chemistry)

František Rypáček (Institute of Macromolecular Chemistry)

Petr Toman (Institute of Macromolecular Chemistry)

Petr Vlček (Institute of Macromolecular Chemistry)

Extended Abstracts

  1. NMR study of order and mobility in supramacromolecular systems
    Jaroslav Kříž 1
  1. Ordered structures in semicrystalline polymers and blends studied by vibrational and NMR spectroscopy

Jiří Dybal, Pavel Schmidt, Jiří Brus 3

  1. Solvent effects on the characteristics of poly(3-alkylthiophene)s
    Chong-Kyu Shin, Sang Joon Lee, Samjoo Lee, Hoosung Lee 5
  2. Poly(organylsilanediyl)s: Charge carrier photogeneration and transport
    Stanislav Nešpůrek 7
  3. Spin and charge dynamics in the conducting poly(phenylenevinylene)s
    Cheol Eui Lee, Jung-Il Jin 9
  1. Quantum mechanical study of quasiparticle conformational defects
    in oligo(phenylenevinylene)

Petr Toman 11

  1. Luminescence of poly(phenylenevinylene) derivatives carrying anthracene, carbazole
    and PBD pendants

Jung-Il Jin 12

  1. Charge photogeneration in substituted polyacetylenes
    Jiří Pfleger 14
  2. Conducting polymer modified electrodes - characterization and applications
    Su-Moon Park 16
  3. Effect of a compatibilizer on the phase structure development in polymer blends
    Ivan Fortelný, Zdeněk Horák, Drahomíra Hlavatá, František Lednický 18
  1. Self-organization of rod-coil molecules with layered crystalline state into thermotropic liquid-crystalline assemblies

Myongsoo Lee, Byoung-Ki Cho, Dong-Woo Lee, Wang-Cheol Zin 20

  1. Enzymatically degradable drug carrier system based on poly(ethylene glycol)
    multiblock copolymers

Michal Pechar, Vladimír Šubr, Karel Ulbrich, Leonard W. Seymour 22

  1. Synthesis and antitumor activities of medium-molecular-weight compounds containing citric
    acid and 5-fluorouracil moieties

Sun-Mi Lee, Chang-Sik Ha, Won-Jei Cho 24

  1. Polyelectrolyte complexes of DNA for gene delivery
    David Oupický, Čestmír Koňák, Leonard W. Seymour, Karel Ulbrich 26
  2. Biodegradable medical polymers with functional groups
    František Rypáček, Milan Dvořák, Rudolf Kotva, Dana Kubies,
    Luďka Machová, Igor Štefko 28
  3. Molecular design and characterization of amphiphilic copolymers for biomedical applications
    Yong Kiel Sung, Seung Jun Han 29
  1. Development of polymer carriers for cultivation and transplantation of keratinocytes on large
    skin defects

Jiří Michálek, Jiří Vacík, Karel Smetana, Barbora Dvořánková, Jiří Labský,
Jaromír Lukáš 33

  1. New hydrogels for encapsulation of living cells
    Jaromír Lukáš, Věra Palečková, Karel Smetana, Barbora Dvořánková 35
  1. Characterization of lacquer coatings on the Koryo Buddhist canon printing wood blocks of the Haein-sa monastery

Choon Ho Do 37

  1. Progress in membrane operations
    Miroslav Bleha 39
  1. Ligated anionic polymerization and atom transfer radical polymerization, efficient ways to tailor-made polymers

Petr Vlček 41

  1. Controlled radical polymerization
    Jan Lokaj 43

Curricula Vitae

Jaroslav Kříž 45

Jiří Dybal 46

Hoosung Lee 47

Stanislav Nešpůrek 48

Cheol Eui Lee 49

Petr Toman 50

Jung-Il Jin 51

Jiří Pfleger 52

Su-Moon Park 53

Ivan Fortelný 54

Myongsoo Lee 55

Michal Pechar 56

Won-Jei Cho 57

David Oupický 58

František Rypáček 59

Yong Kiel Sung 60

Jiří Michálek 61

Jaromír Lukáš 62

Choon Ho Do 63

Miroslav Bleha 64

Petr Vlček 65

Jan Lokaj 66

Karel Ulbrich 67

PROGRAMME

December 1

Chairman: Jung-Il-Jin

Co-Chairman: Jiří Dybal

  9:00 -  9:10 Opening

  9:10 -  9:40 NMR study of order and mobility in supramacromolecular systems

Jaroslav Kříž

  9:40 - 10:10 Ordered structures in semicrystalline polymers and blends studied by vibrational and NMR spectroscopy Jiří Dybal

10:10 - 10:40 Solvent effects on the characteristics of poly(3-alkylthiophene)s

Hoosung Lee

10:40 - 11:00 Coffee break

11:00 - 11:30 Poly(organylsilanediyl)s: Charge carrier photogeneration and transport

Stanislav Nešpůrek

11:30 - 12:00 Spin and charge dynamics in the conducting poly(phenylenevinylene)s

Cheol Eui Lee

12:00 - 12:30 Quantum mechanical study of quasiparticle conformational defects in oligo(phenylenevinylene) Petr Toman

12:30 - 13:30 Lunch

Chairman: Hoosung Lee

Co-Chairman: Stanislav Nešpůrek

13:30 - 14:00 Luminescence of poly(phenylenevinylene) derivatives carrying anthracene, carbazole and PBD pendants Jung-Il Jin

14:00 - 14:30 Charge photogeneration in substituted polyacetylenes Jiří Pfleger

14:30 - 15:00 Conducting polymer modified electrodes - characterization and applications

Su-Moon Park

15:00 - 15:30 Coffee break

15:30 - 16:00 Effect of a compatibilizer on the phase structure development in polymer blends Ivan Fortelný

16:00 - 16:30 Self-organization of rod-coil molecules with layered crystalline state into thermotropic liquid-crystalline assemblies Myongsoo Lee


December 2

Chairman: František Rypáček

Co-Chairman: Yong Kiel Sung

  9:00 -  9:30 Enzymatically degradable drug carrier system based on poly(ethylene glycol) multiblock copolymers Michal Pechar

  9:30 - 10:00 Synthesis and antitumor activities of medium-molecular-weight compounds containing citric acid and 5-fluorouracil moieties Won-Jei Cho

10:00 - 10:30 Polyelectrolyte complexes of DNA for gene delivery David Oupický

10:30 - 11:00 Coffee break

11:00 - 11:30 Biodegradable medical polymers with functional groups František Rypáček

11:30 - 12:00 Molecular design and characterization of amphiphilic copolymers for biomedical applications Yong Kiel Sung

12:00 - 12:30 Development of polymer carriers for cultivation and transplantation of keratinocytes on large skin defects Jiří Michálek

12:30 - 13:30 Lunch

Chairman: Miroslav Bleha

Co-Chairman: Choon Ho Do

13:30 - 14:00 New hydrogels for encapsulation of living cells Jaromír Lukáš

14:00 - 14:30 Characterization of lacquer coatings on the Koryo Buddhist canon printing wood blocks of the Haein-sa monastery Choon Ho Do

14:30 - 15:00 Progress in membrane operations Miroslav Bleha

15:00 - 15:30 Coffee break

15:30 - 16:00 Ligated anionic polymerization and atom transfer radical polymerization, efficient ways to tailor-made polymers Petr Vlček

16:00 - 16:30 Controlled radical polymerization Jan Lokaj

16:30 - 16:40 Closing