Series of 15 new liquid crystalline compounds have been synthesized and studied composed of non-symmetrical bent-shaped molecules based on a 7-hydroxynaphtalene-2-carboxylic acid, the central naphtalene core being laterally substituted by chlorine or the methyl group. Studies of textures in planar samples, calorimetric study, X-ray diffraction and dielectric measurements enabled to establish mesomorphic properties (ie. phase transitions and sequences of phases) of these compounds. The studied compounds exhibit the antiferroelectric B2 phase and relatively scarce polar columnar phases. The full text >>