Přednášející: Martin Setvin (Institute of Applied Physics, TU Vienna, Vienna, Austria)
Místo: Cukrovarnická 10, budova A, knihovna - 1. patro
Jazyk: anglicky
Pořadatelé:
Oddělení tenkých vrstev a nanostruktur
TiO2 is a prototypical metal oxide used in photocatalysis [1], photoelectrochemical (Grätzel) solar cells [2], and transparent conducting oxides [3]. Industrially two forms of TiO2 are used, rutile and anatase. The behavior of charge carriers is of key importance in virtually all applications of these materials. When excess electrons are added to the conduction band of an oxide, the electron-phonon interaction may result in electron trapping – the formation of either localized (small) or delocalized (large) polarons [4].
We used a combination of STM, STS and DFT+U to investigate the nature of electron polarons in rutile and anatase [5,6]. The excess electrons in rutile can localize at any lattice Ti atom, forming a small polaron. The polarons in rutile can easily hop to neighboring sites. Electrons in a perfect anatase lattice prefer delocalized (band-like) solutions, while electron localization is only possible at defects. Delocalized electrons were observed in Nb-doped anatase in vicinity of subsurface Nb dopants. The consequences of different electron behavior in these materials are illustrated on several examples - electrical conductivity, adsorption of simple molecules, and band alignment of rutile/anatase.
The work was supported by ERC Advanced Research Grant ‘Oxide Surfaces’[1] M. A. Henderson, Surf. Sci. Rep. 66, 185 (2011)
[2] M. Gratzel, Nature 2001, 414, 338 – 344
[3] S. X. Zhang et al., J. Appl. Physics 102, 013701 (2007)
[4] I. G. Austin and N. F. Mott, Adv. Phys. 50, 757 (2001)
[5] M. Setvin et al., PRL 113, 086402 (2014)
[6] M. Setvin et al., Angew. Chem. Int. Ed. 53, 4714 (2014)
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