Magnetism of mixed quaternary Heusler alloys: (Ni 1-x,Tx)2 MnSn (T=Cu,Pd) as a case study

Abstract
The electronic properties, exchange interactions, finite-temperature magnetism, and transport properties of random quaternary Heusler Ni2MnSn alloys doped with Cu- and Pd-atoms are studied theoretically by means of ab initio calculations over the entire range of dopant concentrations. While the magnetic moments are only weakly dependent on the alloy composition, the Curie temperatures exhibit strongly non-linear behavior with respect to Cu-doping in contrast with an almost linear concentration dependence in the case of Pd-doping. An analysis of exchange interactions is provided for a deeper understanding of the problem. The dopant atoms perturb electronic structure close to the Fermi energy only weakly and the residual resistivity thus obeys a simple Nordheim rule. The dominating contribution to the temperature-dependent resistivity is due to thermodynamical fluctuations originating from the spin-disorder, which, according to our calculations, can be described reasonably well via the disordered local moment model. The present parameter-free theory agrees qualitatively and also reasonably well quantitatively with all available experimental results.

* In collaboration with S.K. Bose (Brock University), I. Turek, and V. Drchal