Technologické centrum AV ČR, 11.10.2018.
Czech Liaison Office...
The structural ferroelectric-paraelectric transition has been definitely observed by electron diffraction tomography in the tetragonal tungsten-bronze (TTB) Sr0.35Ba0.61Nb2O6.04 (SBN-35) from the paraelectric group P4/mbm to the ferroelectric Pmbm. At 625 K, the refined structure shows that the average structure of SBN-35 is tetragonal with an almost negligible orthorhombic distortion [Fig.1].
Fig. 1: Refined structure of SBN-35 at 625 K.
The combination of structural and broad-band dielectric studies in SBN-35 suggests that ferroelectricity in TTBs in caused by a more complex mechanism than in perovskites. Several excitations were identified related to the multiple mechanisms responsible for the ferroelectric phase transition [Fig.2]:
Fig. 2: Temperature dependences of the frequencies of the different excitations found in SBN-35 and their dielectric contributions.