Electrochemistry of nano-structures at heterogeneous interfaces: Formation, properties and electron transfer reactions.

Abstract:
Research of redox reaction of organic and organometallic compounds that form isolated and organized structures at the interface solution-metallic electrode. Formation of inclusion complexes of the type host-guest inside cavities of cyclodextrins.Mechanism of redox activation inside cavities of cyclodextrins. Mechanism of electron transfer by means of through bonds and through space. Electronic communication of redox centers. Mechanism of nucleation and growth of monomolecular and multilayer films. In situ detection of redox intermediates. Electrode impedance for analysis of film formation. Quantum chemical interpretation of redox reactions.